Biocidal Products Committee opinions on active substance approval, National authorisation and mutual recognition, Understanding the Waste Framework Directive, Tools to prepare and submit SCIP notifications, List of substances subject to the POPs Regulation, Draft recommendation for inclusion in the Authorisation List and consultation, Submitted restrictions under consideration, Harmonised classification and labelling targeted consultations, Consultations on ECHA Executive Director’s requests, PACT - Public Activities Coordination Tool, Information on Candidate List substances in articles, Candidate List of substances of very high concern for Authorisation, Registry of restriction intentions until outcome, Registry of SVHC intentions until outcome, Table of harmonised entries in Annex VI to CLP, Occupational exposure limits - Activity list, Harmonised classification and labelling (RAC), Chapter R.12: Use Descriptor system of ECHA Guidance on information requirements and chemical safety assessment, Candidate list of substances of very high concern for authorisation, Guidance on the safe use of the substance, PACT - Public activities Co-ordination Tool, CAD - Chemical Agents Directive,Art. 3.2, Table A), Directive 2008/68/EC, last amended by Regulation 2019/1243/EU, 25 July 2019, EU. EU. Proposals for new, or updates to existing harmonised classification and labelling of substances. Tanks should have secondary containment, be fire rated and resistant to impact. This Directive establishes rules for the safe transport of dangerous goods between EU countries by road, rail, and waterway. Label elements Signal word Warning Hazard statement Flammable liquid and vapor. inside a watch) or with very low concentrations considered not to pose risks to human health or the environment. Chemical Hazard : Ethanol is a flammable liquid whose vapours can form ignitable and explosive mixtures with air at normal room temperatures. According to the annexes to the directive, storage areas and containers containing chemical substances or mixtures that are classified as hazardous according to the CLP Regulation (1272/2008/EC) must be marked and/or labeled. Alcohol, Cologne spirit, Ethanol, EtOH, Grain alcohol Clear, colorless liquid with a weak, ethereal, vinous odor. Substances Authorized in Manufacture of Regenerated Cellulose Film for Use as FCM (Annex II), Directive 2007/42/EC, 30 June 2007, EU. Hazard statements were adapted to improve readability and may not correspond textually to the hazard statements codes description in the European Union Specific Hazard Statements (EUH) or the. The ‘Hazard classification and labelling’ section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. ECHA organises consultations to get feedback from all interested parties and to gather the widest possible range of scientific information for the regulatory processes. Non-Exhaustive List of Banned Substances, Directive 94/33/EC on Young People at Work, 20 August 1994, as amended by Dir 2014/27/EU, March 5, 2014 (Based on Table 3 of Annex VI to CLP, inter alia), EU. Some substance identifiers may have been claimed confidential, or may not have been provided, and therefore not be displayed. May form explosive mixture with air at very high concentration. The EU Ecolabel may not be awarded to substances or mixtures classified as such. This substance is used by consumers, in articles, by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing. ReAgent is one of the leading chemical suppliers in the UK. If the substance is covered by more than one CLH entry (e.g. A student wants to use a Bunsen burner to heat a test tube of ethanol. Nausea, vomiting, and intoxication are all symptoms of ingestion. Inhalation: High vapor concentrations may cause a burning sensation in the throat and nose, stinging and watering in the eyes. Release to the environment of this substance can occur from industrial use: manufacturing of the substance, in processing aids at industrial sites and as an intermediate step in further manufacturing of another substance (use of intermediates). Ethanol is a flammable liquid. hydraulic liquids in automotive suspension, lubricants in motor oil and break fluids) and outdoor use. This section is based on three sources for information (harmonised classification and labelling (CLH), REACH registrations and CLP notifications). There are a number of reasons why ethanol is hazardous: Ethanol and its vapour are highly flammable, so it’s important to know its flash points. More information about the EC Inventory can be found here. Additionally, E85, the common ethanol blend, is potentially carcinogenic. Please read these safety precautions through carefully before starting off. 2(b)(i), Directive 98/24/EC on Protection of Workers from Chemical Agent-related Risks, 5 May 1998 (Table 3 of Annex VI to CLP, as amended), EU. Pure ethanol will irritate the skin and eyes. Ethanol is used in the management of toxicity due to ingestion of methanol, or ethylene glycol. Guidance on safe use - recommendations by substance registrant on the proper use of the substance in various situations. : Ethanol is extremely flammable and poses a serious risk of fire, and thus burns to persons, when used in conjunction with alcohol burners at laminar flow benches. REACH regulation aims to improve the protection of human health and the environment from the risks that can be posed by chemicals. This substance can be found in products with material based on: paper (e.g. This database contains the ADR's Dangerous Goods List, as implemented by the EU's Directive 2008/68/EC. Hazard classification & labelling Hazard classification and labelling. 4 Alcohol, and its consumption can cause a number of marked changes in behavior. Do not drink anything. If the substance was not covered by the EC Inventory, ECHA attributes a list number in the same format, starting with the numbers 6, 7, 8 or 9. A substance may have its use restricted to certain articles or products and therefore not all the examples may apply to the specific substance. Food Contact Regenerated Cellulose Directive - Authorised Substances, Workplace Signs - minimum requirements & signs on containers and pipes, Waste Framework Directive, Annex III - Waste - Hazardous Properties, Fertiliser Regulation- Annex I, E.3 (chelating and complexing agents), Substances of very high concern identification, Recommendation for the Authorisation List, Getting started with EU chemicals legislation, Classification of substances and mixtures, Harmonised classification and labelling (CLH). Precautionary statements - describe recommended measures to minimise or prevent adverse effects resulting from exposure to a hazardous product or improper storage or handling of a hazardous product. The examples provided are generic examples and may not apply to the specific substance you are viewing. You can do this by: If you are exposed to ethanol in one of the ways we’ve looked at – ingestion, inhalation or skin contact – you need to take immediate steps to limit any ill-effects. the products in which the substance may be used) may refer to uses as intermediate and under controlled conditions, for which there is no consumer exposure. 2. For some entries, the list includes functional classes, maximum and minimum limit values, and other restrictions. Ethanol was first discovered as a by-product of fermenting alcohol, has been used in chemistry since the 1850s, and due to its versatility is now widely used in industry and homes around the world. InfoCards are updated when new information is available. And ethanol is flammable. Ethanol may dissolve fiberglass resin, causing engine damage and possibly allow leakage of explosive gasoline. This site is not fully supported in Internet Explorer 7 (and earlier versions). Despite being common and having myriad uses. If it is drunk in its pure form, it can be lethal or cause coma. You should also ensure that any pipes, as well as the container, are not susceptible to corrosion by ethanol. The described Product category (i.e. No smoking. It even occurs naturally in certain things we consume. When working with flammable liquids such as ethanol care should be taken to eliminate any fire hazards. Can I Use Isopropyl Alcohol Instead of Denatured Alcohol? When in a concentration of more than 50%, ethanol causes local mucosal lesions through dehydration and albumin precipitation. Impurities or additives: When a specific critical property is calculated from industry data and where the majority of data submitters have indicated that the property relates to cases containing impurities and/or additives, then the respective critical property icon is modified with an asterisk (*). This information is only displayed if the substance is well-defined, its identity is not claimed confidential and there is sufficient information available in ECHA’s databases for ECHA’s algorithms to generate a molecular structure. metal, wooden and plastic construction and building materials), indoor use in long-life materials with high release rate (e.g. InfoCards are generated automatically based on the data available at the time of generation. Compendium of Chemical Hazards: Ethanol Page 5 of 15 Incident Management Physicochemical Properties CAS number 64-17-5 Molecular weight 46.07 Formula C 2 H 6 O Common synonyms Ethyl alcohol, grain alcohol State at room temperature Clear, colourless liquid Volatility 59.3 mmHg at 25°C, volatile Specific gravity 0.8 (water = 1) Flammability Highly flammable The CLP Regulation uses the UN Global Harmonised System (GHS) and European Union Specific Hazard Statements (EUH). Move containers from fire area if you can do so without risk. The molecular formula identifies each type of element by its chemical symbol and identifies the number of atoms of each element found in one discrete molecule of the substance. Bondloc Hand Sanitiser Gel (Ethanol) Specific hazards Highly flammable liquid and vapour. While the harmonized list covers many hazardous substances, other ones not listed may also meet the classification criteria in accordance with the CLP. Although chemical hazards are low, there may be considerable effects on Alcoholic drinks contain ethanol, typically 3 to 7% (v/v) (beers), 11 to 14% (v/v) (wines), 30 to 40% (v/v) (spirits). There are a number of reasons why ethanol is hazardous: Ethanol Is Flammable. The Waste Framework Directive aims to protect the environment and human health from the generation and management of waste and to improve efficient use of resources. Dangerous Goods List (RID, Chap. Advice for firefighters Protective actions during firefighting Cool containers exposed to flames with water until well after the fire is out. But what is... read more, In chemistry, pure chemicals refer to substances that only contain one type of fundamental unit, like an atom or... read more, Brick acid is an extremely powerful cleaner for the building trade that, as the name suggests, removes tough debris... read more, Potassium iodide (KI) is a white crystalline solid that is formed by reacting elemental iodine (I) with potassium hydroxide... read more, When buying chemical products online, you will notice that the concentrations are either marked as v/v, w/w or w/v.... read more, Before we look at how ethanol is made, let’s explore what it is and what it’s used for. The information contained herein is based on the present state of our knowledge. The purpose of the information provided under this section is to highlight the substance hazardousness in a readable format. Consumption is dangerous if driving a vehicle or operating machinery. Hazardous … Tanks should have secondary containment, be fire rated and resistant to impact. – get into fresh air as soon as possible and contact the emergency services for help. Precautions for Loading, Unloading, Transport and Storage of Methanol Methanol requires that handlers pay particular attention to two specific hazards in order to avoid accidental release and ignition of methanol and methanol mixtures: 1.) The InfoCard summarises the non-confidential data of a substance held in the databases of the European Chemicals Agency (ECHA). Ethanol is highly inflammable and combustible so keep away from open flame, sparks and ignition sources. This substance is used in the following areas: scientific research and development and building & construction work. This database contains the RID's Dangerous Goods List, as implemented by the EU's Directive 2008/68/EC. Additionally, if containers of ethanol are heated there is a possibility they will explode. While ethanol is consumed when drinking alcoholic beverages, consuming ethanol alone can cause coma and death. It applies the European Agreements on the international transport of dangerous goods by road (ADR) and inland waterways (ADN), and the Regulations concerning the international carriage of dangerous goods by rail (RID). Other release to the environment of this substance is likely to occur from: outdoor use in long-life materials with low release rate (e.g. Details of dossier compliance checks and testing proposal evaluation. Substances for which an agreed set of classification and labelling data has been agreed at EU level by Member States. and precautions for firefighters In case of fire and/or explosion do not breathe fumes. Food Contact Regenerated Cellulose Directive - Authorised Substances, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, FCM and Articles Regulation, Annex I - Authorised Substances, C&L Inventory, Pre-Registration process, EU. Contact with your eyes can cause immediate stinging pain, but may not cause a serious injury. This list contains biological and chemical agents, in accordance with Art. The EC Number is the numerical identifier for substances in the EC Inventory. Classified as a halogen,... read more, Absolute Ethanol Acetic Acid (CH3COOH) Acetone Ammonia Solutions (NH3) Antifreeze Battery Acid Brick Acid Buffer Solutions Caustic Soda Citric Acid (C6H8O7), Deionized Water Demineralised Water Denatured Alcohol (IMS) Dichloromethane (CH2Cl2) Distilled Water EP Water Ethylene Glycol Formaldehyde (CH2O) Glycerol/Glycerine/Glycerin Hydrochloric Acid (HCL), Isopropyl Alcohol Methylated Spirits Methylene Chloride Monopropylene Glycol Nitric Acid (HNO3) Phosphoric Acid (H3PO4) Polyethylene Glycol (PEG) Potassium Hydroxide (KOH) Potassium Permanganate Propylene Glycol, Silver Nitrate (AgNO3) Sodium Hydroxide (NaOH) Sodium Hypochlorite (NaClO) Sodium Thiosulphate Sulphuric Acid (H2SO4) Ultrapure Water Water (Purified) Xylene ...VIEW ALL PRODUCTS. What is the Classification and Labelling Inventory? Do not try and vomit as it can damage mucous membranes and organs. The ‘Hazard classification’ and labelling section uses the signal word, pictogram(s) and hazard statements of the substance under the harmonised classification and labelling (CLH) as its primary source of information. The use information is displayed per substance life cycle stage (consumer use, in articles, by professional workers (widespread uses), in formulation or re-packing, at industrial sites or in manufacturing). The quality and correctness of the information submitted to ECHA remains the responsibility of the data submitter. The molecular structure is based on structures generated from information available in ECHA’s databases. But larger amounts of ethanol in humans can cause coma and death. Burn injury; smoke inhalation. The Support section provides tools and practical guidance to companies which have responsibilities under the EU chemicals legislation. Éthanol 96%, Ph.Eur., extra pur numéro d'article: P075 Version: 5.0 fr Remplace la version de: 27.01.2020 Version: (4) date d’établissement: 27.07.2015 Révision: 16.06.2020 France (fr) Page 1 / 17. Accidental release measures Personal precautions, protective equipment and emergency procedures: Wear protective equipment. Seek medical assistance if the irritation persists. However, substance notifications in the InfoCard are aggregated independently of the impurities and additives. When mixed with air the vapour is explosive, and can travel to the ignition point and flash back. This substance is used for the manufacture of: fabricated metal products, electrical, electronic and optical equipment and machinery and vehicles. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200) - Signal word danger - Pictograms GHS02, GHS07 - Hazard statements H225 Highly flammable liquid and vapor. Take care when you’re handling it. Methanol is highly flammable and toxic. Hazards Of Ethanol. Direct ingestion of more than 10mL can cause permanent blindness by destruction of the optic nerve, poisoning of the central nervous system, coma and possibly death. Learn about side effects, drug interactions, dosages, warnings, and more. It can spread along the ground and collect in compact areas such as tanks, and is a hazard both indoors and outdoors. – lie down and contact the emergency services straight away. This substance can be found in complex articles, with no release intended: machinery, mechanical appliances, electrical/electronic products not covered by Waste Electrical and Electronic Equipment (WEEE) directive (e.g. The vapour can catch fire at 13 °C and is easily ignited by heat or sparks. If there is a substantial ethanol spill, make Hazard(s) identification Physical hazards Flammable liquids Category 3 Health hazards Serious eye damage/eye irritation Category 2 OSHA defined hazards Not classified. Tool showing an overview of substances in various key regulatory processes that authorities are working on. Take care when you’re handling it. This information has not been reviewed or verified by ECHA, and may change without prior notice. IMDG UN3475 Ethanol and gasoline mixture 3 PG II No IATA UN3475 Ethanol and gasoline mixture 3 PG II No Transport in bulk (according to Annex II of MARPOL 73/78 and the IBC Code): Not applicable. Other release to the environment of this substance is likely to occur from: indoor use (e.g. UN proper shipping name ETHANOL Class 3 Transport hazard class(es) Subsidiary risk-Packing group II Marine pollutant No. The Hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and ... ETHANOL reacts violently with acetyl chloride and acetyl bromide [Rose, (1961); Merck 11th ed., 1989]. We do not recommend using any chemical without first consulting the Material Safety Data Sheet which can be obtained from the manufacturer and following the safety advice and precautions on the product label. accelerated corrosion of common containment alloys. If available, additional information on classification and labelling (C&L) is derived from REACH registration dossiers submitted by industry. ETHANOL ABSOLUTE Pictogram Signal word Danger Hazard statements H225 Highly flammable liquid and vapour. Eye contact – flush your eyes for at least 15 minutes and contact the emergency services. Health Hazards Due to Alcohol Abuse Long-term alcohol misuse is associated with liver and cardiovascular disease, cancer, and nervous system damage as well as psychiatric problems such as depression, anxiety, and antisocial personality disorder. 215–540–4, is covered by three harmonisations: 005–011–00–4; 005–011–01–1 and 005–011–02–9), CLH information cannot be displayed in the InfoCard as the difference between the CLH classifications requires manual interpretation or verification. Workplace Signage: Annexes I and III, Directive 92/58/EEC, last amended by Directive 2014/27/EU, 5 March 2014, EU. Do not drink anything. www.globalp.com Contact Information: EMERGENCY TELEPHONE NUMBER (24 hrs): CHEMTREC (800) 424-9300 COMPANY CONTACT (business hours): 800-542-0778 . Table 3 of Annex VI to CLP Regulation); and (2) the Candidate List of substances of very high concern (SVHC). Ensuring there are no naked flames nearby. Ethanol and Ethanol-Blended Fuels . Allow sufficient space to work in. Always wear safety goggles. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. For a detailed overview on identified uses and environmental releases, please consult the registered substance factsheet. Such notifications are required for hazardous substances, mixtures, or articles, manufactured or imported at over 1 kg per annum. Substances approved or for which approval is sought as Biocidal active substances. The database represents a non-exhaustive list of such substances based on: 1) agents of risk groups 3 and 4 under Directive 2000/54/EC; 2) Table 3 of Annex VI to the CLP Regulation; 3) and Annex I of Directive 2004/37/EC. If you are in any doubt about health and safety issues please consult the Health & Safety Executive (HSE). Glycerol/Glycerine/Glycerin (General Use), sell ethanol in sizes ranging from 500ml to 2.5 litres, Removing Sticky Labels with Rubbing Alcohol. Absorption, which occurs swiftly from the gastrointestinal tract, causes euphoria, with subsequent dizziness, inebriation, paralysis, Other release to the environment of this substance is likely to occur from: outdoor use, indoor use (e.g. It characterizes the product with regard to the appropriate safety precautions. Information on applicable regulatory frameworks is also automatically generated and may not be complete or up to date. Substances listed in the EINECS, ELINCS, or NLP inventories. 2(b)(i) - Hazardous Agents, Workplace Signs - minimum requirements & signs on containers and pipes, Waste Framework Directive, Annex III - Waste - Hazardous Properties, Fertiliser Regulation- Annex I, E.3 (chelating and complexing agents), C&L Inventory, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, C&L Inventory, Biocidal active substances, ECHA-8600dbe1-6174-49ec-b025-9cd03d318e49, C&L Inventory, Registration dossier, Other, alcool carburant (agrocarburant- biocarburant), alcool carburant (agrocarburant-biocarburant), Ethyl alcohol (ethanol) agricultural origin (rectified alcohol, pure ethanol), Ethyl alcohol rectified technical mark "B”, Screenwash Ethanol 200-T1 Sprit 95,1% Oden, EC Inventory, C&L Inventory, Biocidal active substances, Registration dossier, Pre-Registration process, Other, CAD - Chemical Agents Directive, Art. 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